Fire from ice
Beneath our seas, reserves of frozen methane hold
more energy than all other fossil fuels put together. But can we get at
them without causing environmental meltdown?
Oct 18, 2006 - Independent-London
Author(s): Ed Caesar
At the bottom of the planet's deepest oceans, and beneath the frozen
shallows of our coldest seas, there is gold.
Gas hydrate, an ice-like crystalline solid that exists in the oceanic
sediment, is a mixture of water and gas - usually methane. It may become
one of the great energy sources of the 21st century, with the power both
to enhance our lives, and, if approached without care, to damage our
planet irreparably. Last week, 100 scientists from 20 countries convened
in Edinburgh to discuss the best way to progress with gas hydrate
research, and it will not be their last meeting.
The key to gas hydrate's great power lies both in its content and its
volume. The highly concentrated levels of methane found in gas hydrate
can yield astonishing energ y returns - one litre of methane hydrate
solid, for instance, would contain 168 litres of methane gas. But when
it comes to the volume of gas hydrate that exists on Earth, opinions are
split. Many scientists believe - and this seems to be the consensus from
those gathered at Edinburgh - that gas hydrates have the potential to
yield twice as much energy as all the world's fossil fuel reserves.
"That amount," says Professor Bahman Tohidi, head of the gas hydrate
unit of Heriot-Watt University's Institute for Petroleum Research, "is
too big to ignore. Even if we were being conservative, and said that
there was only the equivalent amount of gas hydrate as the total amount
of fossil fuels, that is still an enormous quantity.
"But what is also interesting about gas hydrate is where one finds
it. A lot of countries who do not have conventional reservoirs [of oil
or gas], do have hydrate reservoirs. Japan, for instance. India, too. It
is strategically very important for them to be self- sufficient from an
energy viewpoint.
"And these methane hydrates, because they are mainly methane gas, are
regarded as a low-carbon fuel, like natural gas. It's clean - not
totally clean like hydrogen - but low-carbon."
So far, so rosy. But this is not, says Professor Tohidi, the entire
picture. Gas hydrate, despite its potential as a low-carbon fuel, could
wreak untold damage on the atmosphere. Due to the very high methane
content in its structure, a dissociation of methane hydrate into its
constituent parts, methane and water, could lead to staggering levels of
the gas being released into the atmosphere.
With this grim caveat in mind, major countries around the world are
now in a race to discover how to produce energy from methane hydrate.
But the challenges involved are manifold. "Hydrate reservoirs are
different from conventional reservoirs," says Professor Tohidi.
"In traditional reservoirs, the energies are freed. Here, the source
of energy is solid. Because hydrates are like ice, they are already in
formation. So, to produce from them, you have to turn hydrates into
water and gas: you have to dissociate them."
How is it done?
"One technique is to decrease pressure, another is to increase
temperature, and a third is to introduce alcohol, a little like one
would do with antifreeze," says Professor Tohidi. "But the method we are
developing involves CO2. What you do is inject CO2, and produce methane,
because CO2 can also form a hydrate. And CO2 hydrate is more stable,
from a thermodynamic viewpoint, than methane hydrate.
"So, you can inject CO2, and that CO2 will replace the methane, and
release it, so the methane can come out. You kill two birds with one
stone. You get rid of CO2 and you produce the methane."
The technique sounds simple enough. But is only the first step in a
battle with an energy source that is buried deep in the sea bed.
"Yes, the challenges are great," says Professor Tohidi. "One major
issue arises because these hydrates are basically part of the sediment
structure. And if you dissociate the hydrate, there will be emptiness
where there was once hydrate. These are shallow sediments - hydrate
occurs at about 600m below the sea bed - so [the sediments] are not
consolidated. So, if you remove some of the substance from them, they
might subside. And, if they subside, the sea bed will collapse. Then,
the gas could escape freely, which could be incredibly harmful. This is
why we are trying to replace one hydrate with another, but, as I said,
there are challenges.
"The most serious of those challenges is the prevention of a sudden
release of methane gas, which could have an immediate, disastrous impact
on global warming; the sudden release of methane has been fingered as a
culprit in past climate change. Scientists attempting to extract gas
hydrates do not want another catastrophe on their hands."
If one needed an example of the destructive power of gas hydrate, one
need look no further than the Bermuda Triangle. Scientists, including
Professor Tohidi, seriously believe that much of the myth surrounding
this fatal stretch of water can be explained by the prevalence of
dissociating gas hydrate in the sediment, which causes methane to bubble
up through the sea.
"If methane is coming through the water," says Professor Tohidi, "the
density of water will be reduced. A ship floats only because of the
density of the water beneath it, so if you reduce the density, the ship
will sink. Also, if planes are crashing in this area, that could be
explained, too - methane is highly flammable. Explosions could happen.
Even the problem of the radar going all over the place might be
explained by those bubbles of methane coming out.
They might be causing static electricity, and that can change the
magnetic field in the area."
The lesson to be gleaned from this odd tale is that methane's
lowering of the density of water can have serious implications for oil
rigs, too. And that is just one of the reasons why British businesses -
in particular Fugro and BP - are heavily involved in gas hydrate
research and exploration right now. But for all our know- how, Britain
has no hydrate reservoirs of its own (or very few - there may be some in
waters close to the Faroe Islands). Professor Tohidi's research unit,
one of the world's oldest, was brought into existence because of the
dangers gas hydrates were posing to North Sea oil pipelines, where they
were forming due to unique pressure and temperature conditions.
"Yes, I would say Britain's role in the future of gas hydrate can be
influential," says Professor Tohidi. "Even without considering the
energy potential, Britain has an interest in stopping sub-sea
landslides. And Britain certainly has a role to play in climate change.
But as far as energy is concerned, British scientists and companies can
help with production all over the world - and we already have interest
from Taiwan and China, the US and Canada."
If the struggle for oil is the "great game" of the early 21st
century, that game may now be acquiring a new set of rules. The world is
not far away from the first viable, commercial production of energy from
gas hydrates. Japan, for instance, has set the bar - claiming it will
start commercial extraction by 2016. China, too, has recently invested
$100m in gas hydrate research, starting a new 10-year programme to find
and develop the energy source. The US Geological Survey is currently
conducting some of the most advanced work on gas-hydrate production.
And, with the Gulf of Mexico, Alaska, and Siberia all showing the
possibility of viable gas- hydrate reserves, the old sparring partners -
the US and Russia - will surely play major roles in the future of gas
hydrates.
What no one knows is whether gas hydrates can fulfil their potential.
Will the reservoirs be too dispersed? Will the production methods prove
too costly? Will monitoring, rather than exploiting hydrates, become the
main concern for scientists? What we do know is that decisions that have
the power to shape the energy future of the planet will be taken during
the next decade, and to understand them, one could do worse than know a
little about the frozen booty at the bottom of the ocean.
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