Hydrogen 
    Battery Technology for Portable Devices 
    What is a hydrogen battery? 
    
    
    A hydrogen battery is a combination of a fuel cell power module and 
    an energy module based on Hydrogen on Demand® technology. 
    Like a traditional battery, a hydrogen battery converts chemical energy 
    into electrical energy. However, there are important differences. 
    Traditional batteries are sealed systems. The volume of the battery 
    limits the amount of energy the device can supply, which is in turn limited 
    by the amount of active “fuel” material the battery contains. Once that fuel 
    is consumed, the entire battery must either be replaced or recharged. 
    In a hydrogen battery the amount of energy the device can supply is not 
    limited by the volume of the device. Because the hydrogen battery has 
    separate power and energy modules, the hydrogen battery can be refueled and 
    used over and over simply by replacing the energy module (refueling the 
    system). The energy module can be more compact and less expensive than a 
    primary, single use, battery and can be replaced in a moment, instead of 
    recharged for an hour or more. 
    Advantages for hydrogen batteries vs. traditional batteries: 
     
    
      
        | • | The amount of energy possible is easily 
        variable. For a traditional battery to supply energy for a longer time, 
        the size of the entire sealed battery system must increase. A hydrogen 
        battery system sized for a particular power can supply energy as long as 
        it is refueled, keeping the size of the power module constant. | 
      
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        | • | Because the fuel for a hydrogen battery 
        packs more energy per unit volume and weight (energy density) than 
        traditional batteries, the size of a hydrogen battery energy supply 
        increases less with runtime than does a traditional battery. | 
      
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        | • | The cost of obtaining additional energy 
        from a hydrogen battery is simply the cost of the fuel. The cost of 
        additional energy when using traditional primary batteries is that of 
        purchasing more batteries, which can be many times the cost of the fuel. | 
      
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        | • | A hydrogen battery can be “recharged” 
        virtually instantaneously by supplying additional fuel; traditional 
        battery recharging can take considerably longer, and is impossible in 
        the absence of an auxiliary source of electrical power. | 
    
 
    
    Inside the Millennium Cell Hydrogen Battery – Power 
    and Energy 
    Power 
    The power module half of the hydrogen battery is a fuel cell. Of existing 
    fuel cell technologies, the proton exchange membrane fuel cell (PEMFC, or 
    sometimes just PEM) has received significant attention for portable 
    electronic device applications. These fuel cells operate at low temperature 
    (< 80 °C) and use a solid polymer electrolyte. PEM fuel cells have a number 
    of advantages vs. alternative technologies that make them particularly 
    suitable for use in a hydrogen battery. 
    Unlike direct methanol fuels cells (DMFC), which operate on methanol and 
    water and use a complicated process that requires more platinum at the 
    electrodes, PEM systems use a simpler process requiring less costly 
    electrodes. In addition, PEMs are more efficient, deliver higher voltages, 
    and are more compact than a DMFC system of equivalent power. 
    Energy 
    The energy half of a hydrogen battery is, as one might expect, 
    hydrogen. Hydrogen is an ideal fuel for fuel cells because the conversion of 
    hydrogen and oxygen to energy is simple and uncomplicated by side reactions. 
    The only byproduct of a hydrogen fuel cell is water, which typically 
    vanishes into the atmosphere as harmless water vapor. The key practical 
    issue is storing enough hydrogen in the hydrogen battery for it to be 
    useful. 
    There are a several options for storing hydrogen for use in hydrogen 
    batteries, but many have important draw-backs: 
     
    
      
        | • | Compressed hydrogen—the object of great 
        attention for transportation, cannot supply enough fuel from a 
        sufficiently small and light package for a portable device. | 
      
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        | • | Metal hydrides, which absorb hydrogen on 
        charging and release it on use are too heavy for portable use; they also 
        require a local source of hydrogen for reuse and are too expensive to 
        discard after only one use. | 
      
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        | • | Because PEM fuel cells require hydration 
        (wetting) of the membrane, both compressed hydrogen and hydrogen from a 
        metal hydride source require humidification subsystems. | 
      
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        | • | Hydrogen from methanol or other 
        hydrocarbons, formed via a “reformation” process, requires high internal 
        temperatures, complicated fuel processors, slow start-ups and results in 
        carbon dioxide emissions. Purification is also usually required for use 
        on PEM fuel cells. | 
    
 In contrast, reacting chemical hydrides with water is a great way to 
    generate hydrogen. Millennium Cell has developed and publicly demonstrated 
    systems (known as Hydrogen on Demand® or HOD™ systems) utilizing sodium 
    borohydride (NaBH4) as a hydrogen storage medium at power levels 
    ranging from as low as 2 W up to 65 kW. 
    These systems are light, do not require purifiers, complicated fuel 
    processors or high temperatures; they start quickly and do not emit 
    greenhouse gasses.