| Swedish researchers double efficiency of
dye-sensitized solar cells
IPCE of modified DSSCs reaches 44 percent
By Paul Buckley
Power Management DesignLine Europe
(05/01/2009 1:42 PM EDT)
Winchester, UK - The efficiency of a dye-based solar energy device is
claimed to have been more than doubled by researchers from the Royal
Institute of Technology in Stockholm, Sweden.
Licheng Sun and Anders Hagfeldt at the Royal Institute of Technology believe
their device could be combined with more traditional Graetzel-type
dye-sensitized cells to build doubly-active solar cells.
Dye-sensitized solar cells (DSSCs) feature a photo-active anode to harvest
light energy with a dye which passes electrons to an n-type semiconductor
that coats the anode. A reverse type of solar cell has also been developed
which sees dyes interact with p-type semiconductors positioned at a
light-harvesting cathode
Sun and Hagfeldt claim to have improved the performance of the p-type DSSC
by altering the structure of the polyaromatic dye to improve the charge
separation which ensured the light-excited electron and the hole it leaves
behind both travel around the electric circuit instead of directly
recombining. The thickness of the p-type semiconductor (NiO) layer and the
electrolyte composition were also refined.
The researchers claim that the incident photon to current conversion
efficiency (IPCE) of the modified devices has reached above 44 per cent,
more than double the efficiency of previous p-type photocathodes.
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